Tag Archives: Germany

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Chiral separation with microflows

Chiral separation with microflows - How do you separate enantiomers without any kind of chiral recognition between molecules? The answer it seems is to use asymmetric flow in a micro-fluidic channel. According to computer simulations run by scientists in Germany and Sweden, particles will move to different regions of the channel according to their chirality. Once there, they will migrate at different speeds, and thus they can be separated. The researchers say that this approach could lead to significant benefits in the pharmaceutical industry, where chiral separation plays a significant role in drug design. Reference: S Meinhardt et al, Phys. Rev. Lett., 2012, 108, 214504, DOI: 10.1103/PhysRevLett.108.21450

Slinn Pickings

Gas separation with graphene nanopores

Gas separation with graphene nanopores - Scientists in New Zealand, the US and Germany have developed a way of using tiny pores in a graphene sheet to separate different isotopes of helium. By creating nanoscale holes in the material, the researchers calculated that it should be possible to alter the permeability of graphene to allow helium-3 isotopes to tunnel through, while heavier helium-4 isotopes cannot. This approach has potential applications in the production of helium-3 for scientific research as well as for the separation of gases in other scientific and industrial contexts. References: 1 A Hauser, J Schrier and P Schwerdtfeger, J. Phys. Chem. C, 2012, DOI: 10.1021/jp302498d 2 A Hauser and P Schwerdtfeger, J. Phys. Chem. Lett., 2012, 3, 209 (DOI: 10.1021/jz201504k) 3 D Jiang, V R Cooper and S Dai, Nano. Lett., 2009, 9, 4019 (DOI: 10.1021/nl9021946)

Slinn Pickings

Borosulfate breaks through

Borosulfate breaks through - Henning Höppe, together with a team from the University of Augsburg and Albert Ludwigs University Freiburg in Germany, have created potassium borosulfate - K5[B(SO4)4] - by heating potassium sulfate with boric and sulfuric acids. The compound they created comprises a boron atom linked through four oxygen atoms to four sulfate groups and carries a formal 5- charge. Reference: H A Höppe et al, Angew. Chem., Int. Ed., 2012, DOI: 10.1002/anie.201109237